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Bitumen was modified with desulfurized crumb rubber (DCR) in the present of reac tive additives. The effect of the kinds and content of the reactive additive on prop erties of DCR modified bitumen (DCRMB) was investigated. The morphology of DCRMB was characterized by SEM and the changes of the chemical structure of DCRMB wit hout and with the addition of the reactive additive were analyzed by FTIR. The e xperimented results show that the softening point,the elasticity recovery and th e storage stability of DCRMB were improved significantly by the addition of the reactive additive. This is because that a network structure of rubber in DCRMB w as formed and the chemical reaction between C=C double bonds in bitumen and DCR has happened after the reactive additive was added into DCRMB.