【摘 要】
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We have developed an asymmetric ring opening reaction of oxabenzonorbornadienes with substituted phenolic nucleophiles. Under the reaction conditions ( [Rh(COD)
【机 构】
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College of Chemistry and Environment
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We have developed an asymmetric ring opening reaction of oxabenzonorbornadienes with substituted phenolic nucleophiles. Under the reaction conditions ( [Rh(COD)Cl]2 (1 mol%),(S)-(R)-PPF-ptBu2 (2 mol%), THF, reflux), the reaction products were obtained with high yield and enantiomeric excesses ( up to 99% ee).
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