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以N,N′-二(5-四唑基)胺为含能配体设计合成了一个含能配合物[Mn(BTA)(phen)2·5H2O](1)(BTA=N,N′-二(5-四唑基)胺,phen=1,10-phenanthroline),利用元素分析,X射线单晶衍射,红外光谱以及热重分析等手段对标题化合物进行了表征,并研究了配合物1对固体推进剂主要组分HMX热分解行为的影响,结果表明配合物1可以降低HMX的分解峰温.晶体学数据:单斜晶系,P2(1)/c空间群,a=1.0752(6)nm,b=2.6913(14)nm,c=1.0965(6)nm,β=107.953°,V=3.019(3)nm3,Z=4,S=1.010,最终残差因子[I>2σ(I)]R1=0.0420,wR2=0.1084,对于全部数据R1=0.0608,wR2=0.1207.
A complex of [Mn (BTA) (phen) 2 · 5H2O] (1) (BTA = N, N ’ The title compound was characterized by elemental analysis, single crystal X-ray diffraction, infrared spectroscopy and thermogravimetric analysis. The results showed that the complex 1 on the pyrolysis behavior of HMX, the main component of solid propellant, the results show that the decomposition peak temperature of HMX can be reduced by complex 1. Crystallographic data: monoclinic, P2 (1) / c space group, a = 1.0752 The final residual factor [I> 2σ (6) nm, b = 2.6913 (14) nm, c = 1.0965 (6) nm, β = 107.953 °, V = 3.019 (3) nm3, Z = 4 and S = 1.010 I)] R1 = 0.0420, wR2 = 0.1084, R1 = 0.0608 for all data, wR2 = 0.1207.