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The title complex, [Mn3(μ-oxalate)3(μ-4,4-bpy)2(4,4-bpy)2]n, was synthesized and structurally characterized by X-ray crystallography. It crystallizes in the monoclinic, space group P21/c with a = 16.3222(6), b = 16.2594(5), c = 16.4885(5) , β = 94.9900(10)°, V = 4359.3(2) 3, Z = 4, Mn3C46N8O12H32, Mr = 1053.62, Dc = 1.605 g/cm3, F(000) = 2140 and μ(MoKa) = 0.932 mm-1. The structure was refined to R = 0.0578 and wR = 0.1061 for 4795 observed reflections (I > 2σ(I)). The oxalate anions behave as the bridging ligand and link two manganese atoms repeatedly to form infinite one-dimensional chains which further extend into a two-dimensional network by bridging 4,4-bpy ligands.
The title complex, [Mn3 (μ-oxalate) 3 (μ-4,4-bpy) 2 (4,4-bpy) 2] n, was synthesized and structurally characterized by X-ray crystallography. It crystallizes in the monoclinic, Space group P21 / c with a = 16.3222 (6), b = 16.2594 (5), c = 16.4885 (5), β = 94.9900 (10) °, V = 4359.3 (2) 3, Z = 4, Mn3C46N8O12H32, Mr = 1053.62, Dc = 1.605 g / cm3, F (000) = 2140 and μ (MoKa) = 0.932 mm- 1. The structure was refined to R = 0.0578 and wR = 0.1061 for 4795 at reflections (I> 2σ The oxalate anions behave as the bridging ligand and link two manganese atoms repeatedly to form infinite one-dimensional chains which further extend into a two-dimensional network by bridging 4,4-bpy ligands.