【摘 要】
：
The title compound, [Cu(4,4'-bpy)(H2O)4](C4H2O4)(H2O)4 1, has been synthesized by the reaction of Cu(NO3)2·(3H2O with 4,4'-bipyridine and fumaric acid, and str
【机 构】
：
State Key Laboratory of Structural Chemistry
论文部分内容阅读
The title compound, [Cu(4,4'-bpy)(H2O)4](C4H2O4)(H2O)4 1, has been synthesized by the reaction of Cu(NO3)2·(3H2O with 4,4'-bipyridine and fumaric acid, and structurally characterized by X-ray diffraction analysis. Its crystal structure belongs to monoclinic, space group C2/c with a = 16.6350(5), b = 11.1667(2), c = 13.1371(4) A, β = 125.144(1)o, C14H26CuN2O12, Mr = 477.91, Z = 4, V = 1995.47(9) A3, Dx = 1.591 g/cm3, μ = 1.160 mm-1, F(000) = 996, R = 0.0331 and wR = 0.0883 for 1765 observed reflections (I > 2σ(I)). A two-dimensional network is formed in complex 1 through the hydrogen bonds and VDW interactions.
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