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本文研究了CSTR中邻氨基苯甲酸BZ反应体系的振荡行为,总结了非催化条件下各反应物浓度和流速变化以及温度变化对体系振荡反应的影响规律;同时还考察了催化条件下的体系振荡行为,发现了Mn(Ⅱ)催化出现复复杂振荡反应序列,非线性动力学理论分析的结果表明复杂振荡是由体系动力学本质决定的确定性行为,并发现由周期走向混沌的演变过程中存在倍周期分岔(或慢周期分岔)迹象;同时,还通过计算分维,研究反应条件对体系分形结构的影响,从系统相空间几何的现点考察了模拟该体系的数学模型所需最少变量数,为第二部分的模型分析提供了实验依据.
In this paper, the oscillating behavior of anthranilic acid BZ reaction system in CSTR was studied. The influences of concentration and flow rate of each reactant under non-catalytic conditions and the influence of temperature on the system oscillation reaction were also investigated. At the same time, The results show that the complex oscillation is a deterministic behavior determined by the nature of the system dynamics and found that the evolution from periodic to chaotic existence At the same time, through the calculation of fractal dimension, the influence of reaction conditions on the fractal structure of the system was studied. From the point of the system’s phase space geometry, the least number of mathematical models required to simulate the system were investigated The number of variables provides the experimental basis for the second part of the model analysis.