最近,据美国Johns Hopkins大学的K.D.Karlin及其合作者J.A.Zubieta报导,将亚硝鎓离子(NO+)氧化加成至某种双核铜(I)络合物上,然后加以结晶,所得的产物经结构测定,首次证实为是铜-亚硝酰络合物。亚硝酰基(NO)在无机化学中是一种普通的配位体,它与一部份过渡金属易于生成络合物。但从结 Recently, KDKarlin of Johns Hopkins University in the United States and its collaborator JAZubieta reported that nitrosonium ion (NO +) is oxidatively added to some dinuclear copper (I) complex and then crystallized. The resulting product The structure was confirmed for the first time as a copper-nitrosyl complex. Nitrosyl (NO) is a common ligand in inorganic chemistry that readily forms complexes with some transition metals. But from the knot