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动态可逆作用是构筑智能材料体系,实现材料性能可控、可调性的重要工具。但是,多数基于动态可逆作用的智能体系仅能对“开/关”转换的外界刺激因素,如光、热、溶剂、pH等产生响应,不能实现自动调控。化学振荡反应及自振荡高分子材料的发展为新型自调控智能体系的构建提供了重要的思路。本文结合自调控智能体系的最新研究进展,介绍化学振荡反应调控的动态可逆智能体系(DRIS),包括利用动态共价键、主-客体作用、配位作用、离子作用、分子间作用等动态可逆作用构筑的纳米粒子自动聚集/分散体系、两亲性分子自组装/解组装体系、宏观凝胶自组装/解组装体系、自动分子器件、自动荧光振荡体系等。最后,对化学振荡反应调控的动态可逆智能体系的研究与发展进行展望。
Dynamic reversible role is to build intelligent material system to achieve material performance controllable, adjustable an important tool. However, most intelligent systems based on dynamic reversible functions can not only automatically regulate the external stimuli such as light, heat, solvent, pH, etc. that are switched on / off. The chemical oscillatory reaction and the development of self-oscillating polymer materials provide important ideas for the construction of a new self-tuning intelligent system. In this paper, we introduce the dynamic reversible intelligent system (DRIS) which regulates the chemical oscillatory reaction, including the dynamic reversible system using dynamic covalent bond, host-guest interaction, coordination reaction, ionic interaction and intermolecular interaction, The role of the construction of nano-particles automatic aggregation / dispersion system, amphiphilic molecules self-assembly / disassembly system, macroscopic gel self-assembly / disassembly system, automatic molecular devices, automatic fluorescence oscillation system. Finally, the research and development of the dynamic reversible intelligent system which regulates the chemical oscillation reaction are prospected.