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在100m l高压釜反应器内, 用工业Ni-Mo/Al2 O3 催化剂, 于氢初压8.5MPa, 搅拌转速850r/m in, 反应温度663~693K和不同的反应时间下, 进行了孤岛渣油 (GDVR) 的加氢裂化反应实验。通过对已有窄馏分集总动力学模型的分析, 改进了Stangeland 模型, 建立了适用于渣油加氢裂化反应的窄馏分集总动力学模型。该模型适用于原料和产物实沸点蒸馏数据不完整的情况。将其应用于描述渣油加氢裂化反应动力学规律,模型计算结果与实验值一致
In 100m l autoclave reactor, with industrial Ni-Mo / Al2O3 catalyst, hydrogen initial pressure of 8.5MPa, stirring speed 850r / min, the reaction temperature of 663 ~ 693K and different reaction time, isolated island slag Hydrocracking reaction of oil (GDVR). Through the analysis of the existing narrow fraction lumped kinetic model, the Stangeland model is improved and a narrow fraction lumped kinetic model suitable for the residue hydrocracking reaction is established. The model is suitable for the incomplete boiling point distillation of raw materials and products. It is applied to describe the kinetics of resid hydrocracking reaction. The calculated results are consistent with the experimental values