By using the perturbation method,effective nonlinear direct current (DC) and alteating current (AC) responses of nonlinear composites with spherical coated inclusions randomly embedded in a host medium are studied under the action of an exteal electric field Ea =E0 + E1 sin ωt + E3 sin 3ωt with different amplitudes and frequencies.The local potentials of composites at all harmonics are given in the inclusion particles and the host regions.All effective nonlinear responses to composites and the relationship between the effective nonlinear responses at all harmonics are also deduced for the spherical coated inclusions in a dilute limit.