Effects of RE and Al on the structure, impact toughness, hardness, and wear resistance of high chromium cast iron containing wolfram were investigated.The results show that without modification the volume fraction of austenite is high and the carbide appears to be thick lath and the grain size is relatively large;proper modification using RE combined with Al can reduce volume fraction of residual austenite in the as-cast structure obviously, refine grain size of primary austenite notably, and make the morphology of carbide changing from thick lath to thin lath, rosette, and feather-like modification can also increase hardness, wear resistance and impact toughness of cast iron.