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描述了应用Arndt-Eistert反应合成两种含酰胺基的N-Fmoc-L-β-氨基酸的方法,讨论了在Wolff重排过程中,N-Fmoc-L-α-谷氨酰胺重氮甲基酮和N-Fmoc-L-α-天冬酰胺重氮甲基酮的各自特点及反应过程中生成的副产物。
Describes a method for the synthesis of two amide-containing N-Fmoc-L-β-amino acids by the Arndt-Eistert reaction. It is discussed that N-Fmoc-L-α- The respective characteristics of the ketone and N-Fmoc-L-alpha-asparagine diazomethyl ketone and by-products formed during the reaction.