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测定并分析了化合物(Et4_N)_2[Ni_2(SC_6H_4O)_2(μ-SC_6H_4OH)_2]和(Ph_4P)_2[Ni_3(SCH(CH_3)CH_2S)_4]·2CH_3CN的_1H NMR数据,计算了模拟谱,确认它们在DMSO溶液中仍保持原有固体状态的分子结构,它们的抗磁性质得到~(13)C NMR的证实。
The 1H NMR data of the compounds (Et4_N) _2 [Ni_2 (SC_6H_4O) _2] and [Ph_4P] _2 [Ni_3 (SCH (CH_3) CH_2S) _4] · 2CH_3CN were measured and analyzed. , Confirming that they still maintain the original solid state molecular structure in DMSO solution and their diamagnetic properties are confirmed by ~ (13) C NMR.