兰姆移位的一种半定量计算方法

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考虑一个自由电子以动量p运动时因吸放虚光子而引起自能的辐射修正,用非协变形式的量子微扰论算出它有b2p4的形式. 在此基础上加上真空极化修正和核有限半径引起的修正,算得氢原子2S1/2-2P1/2态的兰姆移位为1056.522 MHz,比实验值1057.845 MHz仅小0.13%.用Dirac方程作相对论性修正后,还计算了氢原子4D5/2-4S1/2态的能级差,所谓"超兰姆移位"和1S态的"绝对"兰姆移位. 误差最大达6.7%,并分析了原因.
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