所谓配位化合物必然是伴有参与络合的给体原子与受体原子间配位键的形成,Mulliken曾从理论上指出这种配位键是给体分子的非键电子到受体分子的空轨道的电子电荷转移的结果。而XPS所测 The so-called coordination compounds must be accompanied by the formation of complex coordination between the donor atoms and the acceptor atoms, Mulliken has theoretically pointed out that this coordination bond is a donor molecule non-bond electrons to the acceptor molecule The result of electron or charge transfer from an empty orbit. The XPS measured