Molten Salt Derived Graphene-Like Carbon Nanosheets Wrapped SiOx/Carbon Submicrospheres with Enhance

来源 :中国化学(英文版) | 被引量 : 0次 | 上传用户:ineedtoxiazai
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
Main observation and conclusionrnThere is no doubt that SiOx and carbon composite is one of the promising anode materials for lithium-ion batteries owing to its high capacity and rational cycling stability.Herein,we report a sol-gel synthesis followed by molten salt carbonization route to fabricate graphene-like carbon nanosheet wrapped SiOx/C submicrospheres (SiOx/C@2D-C).The in-situ generated carbon nanosheets under molten salt condition can further improve the electroconductivity,restrain the volumetric expansion and guarantee the structural in-tegrity of the electrode.As a result,the as-obtained SiOx/C@2D-C delivers a discharge capacity of 559 mAh·g-1 at 0.5 A·g-1 after 200 cycles and 548 mAh·g-1 at 1.0 A·g-1 even after 1000 cycles.The full cell assembled with SiOx/C@2D-C as anode and commercial LiFePO4 as cathode can achieve an energy density of 200 Wh·kg-1 and maintain a capacity of 66.7% after 100 cycles with a working potential of 2.8 V.The approach is simple and cost effective,which is promising for mass production of SiOx-based materials for high energy LIBs.
其他文献
Catalytic asymmetric transformations involving carbon-carbon bond cleavages open intriguing strategies for the synthesis of chiral complex molecules.The transient organometallic species mainly generate from the oxidative addition of cyclic compounds with
Annual Land Use/Land Cover(LULC)change information at medium spatial resolution(i.e.,at 30 m)is used in applications ranging from land management to achieving sustainable development goals related to food security.However,obtaining annual LULC information
Main observation and conclusionrnIt is highly urgent to develop synthetic strategies to make new category of stable luminescent radicals with desired emission wavelength.In this study,we have isolated two dioxoborocyclic radicals (3 and 4) by a direct syn
Since the introduction of the concept of frustrated Lewis pair by Stephan in 2006,the frustrated Lewis pair (FLP) chemistry has evolved into a rich and fruitful research area which is largely responsible for the renaissance of main group chemistry in rece
Baseflow,a component of the total streamflow,plays a key role in maintaining aquatic habitats,particularly during extreme drought events.This study investigated baseflow response to a prolonged and extreme meteorological drought event in the Baiyangdian B
Main observation and conclusionrnWe report herein a Re-based tricarbonyl catalyst [fac-Re(L1)(CO)3Cl] (Re1) bearing a spiro center and a phenol group as a local proton source in the second coordination sphere.Due to the large steric spiro group,dimerizati
Biochar amendment is considered as an efficient practice for improving carbon storage in soils.However,to what extent that biochar application promotes organic carbon in saline-sodic soils remains poorly understood.By comparing soil organic carbon (SOC)co
Main observation and conclusionrnEthanol is considered a better fuel than methanol in direct alcohol fuel cells because of the high energy density and low toxicity.Compared with noble metal catalysts,nickel-based catalysts are much cheaper in price.Howeve
In recent years,O2O e-commerce,represented by online group-buying,has developed vigorously,which had significant im-pacts on urban commercial space.Zhengzhou City is a rising national central city in China,and its e-commerce development level is ahead,but
Main observation and conclusionrnThree zwitterionic and one cationic N-heterocyclic allenylidene (NHA) platinum(Ⅱ) complexes were prepared and characterized via NMR,HR-MS,and FT-IR,etc.Single crystal structure analyses revealed the various intermolecular