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One new complex has been produced under solvothermal reactions of tetrakis(4-pyridyloxymethylene)methane(TPOM) with glutaric acid(GA) in the presence of nitrates of cuprum in DMF/H2O(1:5, v/v), namely, {Cu2(TPOM)·GA)2}n. The complex crystallizes in the monoclinic system, space group P2/c with a = 11.556(4), b = 8.713(3), c = 23.602(9) ?, V = 2376.5(15) ?3, C35H36Cu2N4O12, Mr = 831.76, Z = 2, Dc = 1.162 g·cm-3, F(000) = 856, μ = 0.947mm-1, R = 0.0547 and wR = 0.1718(I > 2σ(I)). This complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It is the first complex synthesized by coordinating with TPOM and catenulate aliphatic polycarboxylate acid ligands. The structural analyses show that the complex is a 2-fold interpenetrating 3D architecture.
One new complex has been produced under solvothermal reactions of tetrakis (4-pyridyloxymethylene) methane (TPOM) with glutaric acid (GA) in the presence of nitrates of cuprum in DMF / H2O Cu2 (TPOM) · GA) 2} n. The complex crystallizes in the monoclinic system, space group P2 / c with a = 11.556 (4), b = 8.713 (3), c = 23.602 (9) (15)? 3, C35H36Cu2N4O12, Mr = 831.76, Z = 2, Dc = 1.162 gcm- 3, F000 = 856, μ = 0.947mm- 1, R = 0.0547 and wR = 0.1718 (I> 2σ (I). This complex was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It is the first complex synthesized by coordinating with TPOM and catenulate aliphatic polycarboxylate acid ligands. The structural analyzes show that the complex is a 2-fold interpenetrating 3D architecture.