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本文在文献[1]的基础上,进一步研究了正烷烃C_nH_(2n+2)及其它19个非共轭体系的60组光电子能谱,发现它们的各级垂直电离势也符合同系能级线性规律或同系线性规律,但线性相关系数前者比后者更好一些。
Based on the literature [1], 60 sets of photoelectron spectra of normal paraffin C_nH_ (2n + 2) and other 19 non-conjugated systems were further studied. It was found that their vertical ionization potentials at all levels are also in line with the homology level linearity Law or homology linear law, but the linear correlation coefficient is better than the latter.