氟有机化学是近三十年来发展很快的一门学科。回顾从1886年Moissan制得元素氟,至今已九十七年了,如果我们把其发展过程粗略地划分一下,约为三个阶段;从1886—1925年,在此期间,由于人们对C—F链化合物了解很少,以及当时研究条件的限制等原因,只有少数化学家从事某些C—F链合物制备的探索,所以在这期间进展不大。第二阶段大约从1926—1948年,这是有机氟化学的发展时期,在此期间有几项重大意义的成果出现。1926年制备出第一个简单的碳氟化物CF_4。1930年氟利昂 CF_2Cl_2开始用于冷 Fluorine organic chemistry is a rapidly developing discipline in the past 30 years. Recalling the elemental fluorine produced by Moissan in 1886, which has been 97 years old. If we roughly divide the development process into about three stages, from 1886 to 1925, in the meantime, Little was known about F-chain compounds, and the limitations of the research conditions at that time included only a few chemists engaged in the exploration of the preparation of certain C-F-conjugates, so little progress was made during this period. The second phase, from about 1926 to 1948, was a period of development of organofluorine chemistry, during which several significant results emerged. In 1926, the first simple carbon fluoride CF_4 was prepared. In 1930, wearing CF CF_2Cl_2 was started for cold