合成标题化合物［（ｓｅｄａ）Ｃｕ］·ＥｔＯＨ，并得到单晶［ｓｅｄａ＝Ｎ，Ｎ′－二水杨叉基－１，２－二－（４－甲氧基苯基）乙二胺］．Ｘ－衍射结构分析表明，晶体属正交晶系，空间群Ｐｂｃａ，晶体学数据：ａ＝２．０１１５（４）ｎｍ，ｂ＝１．３１９６（３）ｎｍ，ｃ＝２．１０５７（４）ｎｍ，晶胞体积Ｖ＝５．５８９（３）ｎｍ３，分子量５８８．１６，Ｚ＝８，Ｄｘ＝１．３９８ｇ／ｃｍ３，μ＝８．２３９ｃｍ－１，Ｆ（０００）＝２４６５，最终偏离因子Ｒ＝０．０７９，Ｒｗ＝０．０８３，（Δ／σ）ｍａｘ＝０．６８．结构分析表明，配体中二个偶氮甲碱中氮原子和二个酚氧原子与中心Ｃｕ原子配位，形成规则的菱形平面结构． The title compound [(seda) Cu] EtOH was synthesized and gave a single crystal [seda = N, N’-disalicylidene-1,2-di- (4-methoxyphenyl) ethylenediamine]. X-ray diffraction analysis showed that the crystal belongs to orthorhombic and space group Pbca. The crystallographic data are as follows: a = 2.0115 (4) nm, b = 1.3196 (3) nm, c = 2.1057 nm, unit cell volume V = 5.589 (3) nm3, molecular weight 588.16, Z = 8, Dx = 1.398g / cm3, μ = 8.239cm- 1, F (000) = 2465, final deviation factor R = 0.079, Rw = 0.083, (Δ / σ) max = 0.68. The structural analysis shows that the two azomethine nitrogen and two phenolic oxygen atoms in the ligand coordinate with the central Cu atom to form a regular diamond planar structure.