Synthesis and fluorescence properties of cerium-KMgF_3 through a solvothermal process

来源 :Chinese Chemical Letters | 被引量 : 0次 | 上传用户:beryl1830
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Phosphor of KMgF_3:Ce~(3+)is synthesized through solvothermal method at 180℃and characterized by means of X-ray powder diffraction(XRD)and environment scanning electron microscopy(ESEM).X-ray photoelectron spectroscopy(XPS)is applied to the study of the energy band structure of KMgF_3:Ce~(3+)and confirms the oxygen content of the product is very low.The fluorescence spectra of the rare-earth ion-doped KMgF_3 is investigated by the fluorescence spectrophotometer.In the emission spectra,there is a broadband emission with a maximum center located at 306 nm arising from d-f transition of Ce~(3+)in the host.This will be useful for ultraviolet tunable lasers. Phosphor of KMgF_3: Ce ~ (3+) is synthesized through solvothermal method at 180 ° C and characterized by means of X-ray powder diffraction (XRD) and environment scanning electron microscopy (ESEM). X-ray photoelectron spectroscopy to the study of the energy band structure of KMgF_3: Ce ~ (3+) and confirms the oxygen content of the product is very low. The fluorescence spectra of the rare-earth ion-doped KMgF_3 are investigated by the fluorescence spectrophotometer. the emission spectra, there is a broadband emission with a maximum center located at 306 nm arising from df transition of Ce ~ (3+) in the host. This will be useful for ultraviolet tunable lasers.
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