Bulk metallic glass rings have the potential applications as annular gasket and active solder in special fields. The bulk metallic glass ring of Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 with the outer diameter,the inner diameter,and the thickness of 38,36,and 5 mm,respectively,was prepared by using a special shaped quartz tube water quenching method. The mechanical properties along the whole cross section were investigated by a nanoindentation method,and no evident variation of the Young’s modulus and hardness was found,further indicating the single amorphous structure. Amorphous ring and tube-shape parts with different dimensions can be produced by this method. Bulk metallic glass rings have the potential applications as annular gasket and active solder in special fields. The bulk metallic glass ring of Zr41.2Ti13.8Cu12.5Ni10.0Be22.5 with the outer diameter, the inner diameter, and the thickness of 38, 36, and 5 mm, respectively, was prepared by using a special shaped quartz tube water quenching method. The mechanical properties along the whole cross section were investigated by a nanoindentation method, and no evident variation of the Young’s modulus and hardness was found, further indicating the single amorphous structure. Amorphous ring and tube-shape parts with different dimensions can be produced by this method.