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A new bimetallic complex containing Zn and La was prepared from a salen ligand possessing methoxyl groups at the 3, 3′-positions. The structural feature is that one of nitrate groups is disordered and displaced between two metal centers. Crystal system: Triclinic space group:P-1, Z=2. a=0.82714(17) nm, b=1.3484(3) (1) nm, and c=1 3898(3) (1) nm, α=79.89(3)°, β=76.67(3)°, and γ=72.43(3)°. V=1 428 6(5) nm3, Dx=1.812 g·cm-3. (Δρ)max=1 510×10-3 enm3, (Δρ)min=-1.503×10-3 enm3. Accordingly, two water molecules occupy the metal centers in the apical positions via the syn-geometry.
A new bimetallic complex containing Zn and La was prepared from a salen ligand possessing methoxyl groups at the 3, 3’-positions. The structural feature is that one of the groups of nitrate is disordered and displaced between two metal centers. Crystal system: Triclinic space group A = 0.82714 (17) nm, b = 1.3484 (3) (1) nm, and c = 1 3898 (3) (1) nm, α = 79.89 = 76.67 (3) ° and γ = 72.43 (3) °. V = 1 428 6 (5) nm3, Dx = 1.812 g · cm -3. (Δρ) max = 1 510 × 10 -3 enm3, ) min = -1.503 × 10 -3 enm3., Two water molecules occupy the metal centers in the apical positions via the syn-geometry.