【摘 要】
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Photopromoted carbonylation of alkyl halides with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such
【出 处】
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Chinese Chemical Letters
论文部分内容阅读
Photopromoted carbonylation of alkyl halides with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts. Our preliminary work showed that alkyl halides can be transformed into alkene and alkane directly under irradiation, but the esters can not be transformed. It is assumed that the carbonylation of alkyl halides may be proceeded in two ways.
Photochromic carbonylation of alkyl halides with carbon monoxide can be carried out under ambient conditions with non-precious transition metal complexes (such as cobalt complexes) catalysts. Our preliminary work showed that alkyl halides can be transformed into alkene and alkane directly under irradiation, but the It is assumed that the carbonylation of alkyl halides may be proceeded in both ways.
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