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由异氰酸酯制备伯胺的新方法ＭａｌａｎｇａＣ等［ＴｅｔｒａｈｅｄｒｏｎＬｅｔｔ，１９９５；３６：８８５９］脂族异氰酸酯与Ｈｇ（ＯＡｃ）２在５０％ＴＨＦ／Ｈ２Ｏ中反应４５ｍｉｎ，再加入ＮａＢＨ４的５％ＮａＯＨ溶液，可得相应的伯胺。此反应不受立体位阻影响，...
New method for the preparation of primary amines from isocyanates MalangaC et al [Tetrahedron Lett, 1995; 36: 8859] The reaction of aliphatic isocyanates with Hg (OAc) 2 in 50% THF / H2O for 45 min followed by addition of NaBH4 in 5% Of primary amine. This reaction is not affected by steric hindrance, ...