本文通过控制聚合和后处理条件,首次合成了可溶性聚(o-,m-)甲苯胺,用IR,NMR,VPO和元素分析等手段表征了可溶聚合物。结果表明,按两种方法制备的可溶与不溶聚合物具有相同的电导率和链结构。可溶聚合物主链中含有约28个单体单元,苯式(B)与醌式(Q)的比例约为3:1。并由可溶聚合物制备了自支撑膜,掺杂了的自支撑膜具有与粉末同样的电导率和环境稳定性。 Soluble poly (o-, m-) toluidine was synthesized for the first time by controlling the conditions of polymerization and aftertreatment. Soluble polymers were characterized by IR, NMR, VPO and elemental analysis. The results show that both soluble and insoluble polymers prepared by the two methods have the same conductivity and chain structure. The soluble polymer backbone contains about 28 monomer units with a ratio of about 3: 1 for the benzo (B) to quinone (Q) groups. Self-supporting films were prepared from soluble polymers. The doped self-supporting films had the same conductivity and environmental stability as powders.