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文中借助于热化学循环分别导出了金属在其自身熔盐以及其他熔盐中的溶解度与相应体系电负性的关系。提出了金属在混合熔盐中溶解的阳离子规则和阴离子规则以及计算不同浓度混合熔盐体系中阳离子或阴离子平均电负性的方法。文中列举事实表明上述关系和规则广泛适用并从能量的角度对金属溶解的机理有所分析。
In this paper, the relationship between the solubility of the metal in its own molten salt and other molten salts and the corresponding electronegativity of the corresponding system is deduced by means of the thermochemical cycle. The rules of the cation and anion of the metal dissolved in the mixed molten salt and the method of calculating the average electronegativity of the cation or anion in the mixed molten salt system with different concentrations were proposed. The facts cited in the article show that the above relationships and rules are widely applicable and that the mechanism of metal dissolution is analyzed from an energy standpoint.