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Using Bu4N[Fe(Tp*)(CN)3]- (Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) as the building block to react with CuII and N-methylimidazole, we obtained a one-dimensional (1D) heterobimetallic cyano-bridged chain, [Fe(Tp*)(CN)3]2Cu(N- methylimidazole)2·2H2O (1). The crystal structures and magnetic studies demonstrate that complex 1 exhibits slow relaxation of the magnetization due to strong intrachain ferromagnetic coupling and weak interchain interactions.
Using Bu4N [Fe (Tp *) (CN) 3] - (Tp * = hydrotris (3,5-dimethylpyrazol- 1 -yl) borate) as the building block to react with CuII and N-methylimidazole, (1D) heterobimetallic cyano-bridged chain, [Fe (Tp *) (CN) 3] 2Cu (N- methylimidazole) 2 · 2H2O (1). The crystal structures and magnetic studies demonstrate that complex 1 exhibits slow relaxation of the magnetization due to strong intrachain ferromagnetic coupling and weak interchain interactions.