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本文首次制得了二价稀土与含硫有机配体的固态配合物RE(SSCNC_(13)H_(11)NO)_2·xH_2O(RE=Sm,Eu,Yb,x=3,4),研究了它们的性质,并对二价及相应的三价稀土配合物在物理化学性质上的差异进行了探讨。
In this paper, the solid complex RE (SSCNC_ (13) H_ (11) NO) _2.xH_2O (RE = Sm, Eu, Yb, x = 3,4) of divalent rare earth and sulfur- Their properties, and bivalent and the corresponding trivalent rare earth complexes in physical and chemical properties of the differences were discussed.