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用MonteCarlo方法对选择性溶剂中两嵌段共聚高分子在固液界面的吸附进行了模拟 ,获得了吸附等温线以及吸附层厚度、链附着率、表面覆盖率、链节浓度分布等表征吸附层结构的信息 ,同时模拟获得了固液界面区吸附构型大小及分布等表征高分子构型的微观信息 ,考察了吸附性链节A所受的对比排斥能、链组成以及体相浓度等因素对这些参数的影响 .
Monte Carlo method was used to simulate the adsorption of diblock copolymer on the solid-liquid interface in selective solvent. The adsorption isotherms as well as the adsorption layer thickness, chain attachment rate, surface coverage and chain concentration distribution were obtained. Structure information and simulate the micro-information of the polymer structure in the solid-liquid interface area, such as the size and distribution of the adsorption configuration, the contrast repulsion energy, the composition of the chain and the concentration of the bulk phase Impact on these parameters.