论文部分内容阅读
对Ln~(3+)(Nd~(3+),Ho~(3+),Er~(3+))-1-苯基-3-甲基-4-二氯乙酰基毗唑酮-5(HPMDCP)-二安替吡啉甲垸(DAM)体系乙醇,水溶液的分光光度法研究及对固态钕配合物的元素分析证实:三元配合物的组分比为Ln~(3+):HPMDCP:DAM=1:3:1,研究了钕的配合物的红外吸收光谱和热稳定性;计算了相应配合物的超灵敏跃迁的振子强度,并讨论了振于强度的增值与配体数目的关系及振子强度间的线性关系。
The effects of Ln ~ (3 +) (Nd ~ (3 +), Ho ~ (3 +) and Er ~ (3 +)) The spectrophotometric study of 5 (HPMDCP) -diappeninol (DAM) system for ethanol and aqueous solution and the elemental analysis of the solid neodymium complex confirmed that the composition ratio of the ternary complex is Ln ~ (3+) : HPMDCP: DAM = 1: 3: 1, the infrared absorption spectra and thermal stability of neodymium complexes were studied. The oscillator strengths of the supra-sensitive transitions of the corresponding complexes were calculated. The relationship between the number and the linear relationship between oscillator strength.