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本研究合成了一种新的化合物 :(Ph CMe2 CH2 ) 3Sn Fe(CO) 2 Cp,并对该化合物的结构进行表征 .结果表明 :元素分析结果与相应的化学式的理论值基本相符 ;红外光谱证明了化合物中各种官能团的存在 ;X光四圆衍射仪对所含Sn、Fe单晶的结构测定结果表明 ,该化合物分子中存在 Sn— Fe金属—金属键 .该化合物在水、空气中相当稳定 ;易溶于四氢呋喃、甲苯、己烷
In this study, a new compound (Ph CMe2 CH2) 3Sn Fe (CO) 2 Cp was synthesized and the structure of the compound was characterized.The results showed that the elemental analysis was in good agreement with the theoretical value of the corresponding chemical formula. The infrared spectrum The existence of various functional groups in the compounds was proved. The results of X-ray four-circle diffractometer for the determination of Sn and Fe single crystals show that the compound has Sn-Fe metal-metal bond in water and air Very stable; soluble in tetrahydrofuran, toluene, hexane