【摘 要】
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The bonding of complexes [EuCl3(THF)4] , [NdCl3(THF)4] and [UI3 (THF)4] has been studied by using SCC-DV-Xa method. It was found that THF helps to construct a
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The bonding of complexes [EuCl3(THF)4] , [NdCl3(THF)4] and [UI3 (THF)4] has been studied by using SCC-DV-Xa method. It was found that THF helps to construct a polyhedral molecule and therefore considerably shortens M-X distances. The behaviour of f-orbitals in bonding was studied and discussed herein.
The bonding of complexes [EuCl3 (THF) 4], [Nd3 (THF) 4] and [UI3 (THF) 4] has been studied by using SCC-DV-Xa method. It was found that THF helps to construct a polyhedral molecule and therefore due shortens MX distances. The behavior of f-orbitals in bonding was studied and discussed herein.
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