Seasonal freeze–thaw processes have led to severe soil erosion in the middle and high latitudes. The area affected by freeze–thaw erosion in China exceeds 13％ of the national territory. So understanding the effect of freeze–thaw on erosion process is of great significance for soil and water conservation as well as for ecological engineering. In this study, we designed simulated rainfall experiments to investigate soil erosion processes under two soil conditions, unfrozen slope (UFS) and frozen slope (FS), and three rainfall intensities of 0.6, 0.9 and 1.2 mm/min. The results showed that the initial runoff time of FS occurred much earlier than that of the UFS. Under the same rainfall intensity, the runoff of FS is 1.17–1.26 times that of UFS; and the sediment yield of FS is 6.48–10.49 times that of UFS. With increasing rainfall time, rills were produced on the slope. After the appearance of the rills, the sediment yield on the FS accounts for 74％–86％ of the total sediment yield. Rill erosion was the main reason for the increase in soil erosion rate on FS, and the reduction in water percolation resulting from frozen layers was one of the important factors leading to the advancement of rills on slope. A linear relationship existed between the cumulative runoff and the sediment yield of UFS and FS (R2>0.97, PFS0.6 (72.30 μm)>UFS1.2 (72.23 μm)>substrate (71.23 μm)>FS1.2 (71.06 μm)>FS0.9 (70.72 μm). During the early stage of the rainfall, the MWD of the FS was relatively large. However, during the middle to late rainfall, the particle composition gradually approached that of the soil substrate. Under different rainfall intensities, the mean soil erodibility (MK) of the FS was 7.22 times that of the UFS. The ratio of the mean regression coefficient C2 (MC2) between FS and UFS was roughly correspondent with MK. Therefore, the parameter C2 can be used to evaluate soil erodibility after the appearance of the rills. This article explored the influence mechanism of freeze–thaw effects on loess soil erosion and provided a theoretical basis for further studies on soil erosion in the loess hilly regions.