论文部分内容阅读
Based on Onsager and Onsager-Fuoss-Chen equations of conductance,a new prediction equation is proposed for dilute electrolyte solution. It is used to predict and calculate the conductance of some single strong electrolyte solutions and their mixtures at 298.15 K. The results show good agreements with those data from literatureand they are better than those calculated with Onsager limiting equation and two-parameter Onsager-Fuoss-Chen equation. In addition,the new equation can also be used to determine the limiting molar conductivityof strong electrolyte by one-point experimental data of the molar conductivityat a certain concentration.The calculation deviation of the new equation shows a minimum value when the strength of ion in solution approaches 0.001 mol·dm~-3,hence,so long as the molar conductivity near this point is measured,the limitingmolar conductivity can be calculated conveniently and reliably by the new equation.
Based on Onsager and Onsager-Fuoss-Chen equations of conductance, a new prediction equation is proposed for dilute electrolyte solution. It is used to predict and calculate the conductance of some single strong electrolyte solutions and their mixtures at 298.15 K. The results show good agreements with those data from literature and they are better than those calculated with Onsager-limiting equation and two-parameter Onsager-Fuoss-Chen equation. In addition, the new equation can also be used to determine the limiting molar conductivity of strong electrolyte by one-point experimental data of the molar conductivity of a certain concentration. the calculation deviation of the new equation shows a minimum value when the strength of ion in solution approaches 0.001 mol · dm ~ -3, hence, long as the molar conductivity near this point is measured, the limitingmolar conductivity can be calculated conveniently and reliably by the new equation.