The diversities of hydrogen sorption properties of Mg2FeH_6-based complexes with and without TiO_2 were investigated. Mg_2FeH_6-based complexes with and without TiO_2 were synthesized respectively by reactive mechanical alloying, and hydrogen sorption properties of the complexes were examined by Sieverts-type apparatus. The results show that the sample without TiO_2 releases 4.43 % (mass fraction) hydrogen in 1.5 ks at 653 K under 0.1 MPa H_2 pressure and absorbs 90% of the total 4.43 % (mass fraction) hydrogen absorbed in 85 s at 623 K under 4.0 MPa H2 pressure. But for the sample with TiO_2 addition under the same condition, it only needs 400 s to release all of the stored hydrogen and 60 s to absorb 90% of the total hydrogen absorbed. The activation energies for desorption process of the samples with and without TiO_2 are determined to be 71.2 and 80.3 kJ/(mol·K), respectively. The improvement in hydrogen sorption rate and and reduction in activation energy can be attributed to the addition of TiO_2.