Determination of Vanadyl Porphyrins by Liquid-liquid Microextraction and Nano-baskets of p-tert-Cali

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Dispersive liquid-liquid microextraction technique was introducd to remove the centrifuging step and conduct inclusion microextraction of charged porphyrins by nano-baskets.For nano-baskets ofp-tert-calix[4]arene bearing di-[N-(X)sulfonyl carboxamide] and di-(1-propoxy) in ortho-cone conformation was synthesized and used.The related parameters including ligand concentration,the volume of water disperser,salt effect,and extraction time were optimized.The linear range,detection limit(S/N=3) and precision(RSD,n=6) were determined to be 0.2-50,0.07 μg/L and 5.3%,respectively.The results reveal that the new approach is competitive analytical tool and an alternative of the traditional methods in the crude oil and related systems.
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