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Fe_3(CO)_(12)与亚磷酸三硫代苯酯P(SC_6H_5)_3在温和条件下反应给出三个具有桥联原子的双核铁羰基簇合物(μ-SC_6H_5)_2Fe_2(CO)_5,(μ-SC_6H_5)(μ-P(SC_6H_5)_2)Fe_2(CO)_5和(μ-SC_6H_5)(μ-P(SC_6H_5)_2))Fe_2(CO)_5(P(SC_6H_5)_3).本文对这三个簇合物进行了IR,~1HNMR和MS谱的表征工作,并用z-ray衍射技术测定了它们的单晶结构.
The reaction of Fe_3 (CO) _ (12) with thiodiphenyl phosphite (SC_6H_5) _3 under mild conditions gave three binuclear iron carbonyl clusters (μ-SC_6H_5) _2Fe_2 (CO) (Μ - P (SC_6H_5) _2) Fe_2 (CO) _5 and (μ_SC_6H_5) (μ_P_ (SC_6H_5) _2)) Fe_2 (CO) _5 (P_ (SC_6H_5) __). In this paper, IR, ~ 1HNMR and MS spectra of these three clusters were characterized and their single crystal structures were determined by z-ray diffraction.