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By using different anionic ancillary ligands, two new coordination polymers, [Cd(L)I_2]_n(1) and {[Cd(L)_2(1,4-bdc)]·H_2O}_n(2)(L = 2,4,6-tris(4-pyridyl)pyridine, 1,4-H_2bdc = benzene-1,4-dicarboxylic acid), have been synthesized under hydrothermal c