论文部分内容阅读
Soivothermal reaction of[WS4]2-with CuCN and trithiocyanuric acid(L1)in orga-nic solvents gave rise to a new W/Cu/S polymer with a 2D anionic network,namely[Et4N]2[WS4Cu3(C3N3S3H1.5)2](1).The anionic layer of 1 is constructed by the T-shaped {WS4Cu3}subunits as nodes and L1 as linkers and features a(4,4)topology.Both 1 and its isomorphous compound[Et4N]2[MoS4Cu3(C3N3S3H1.5)2](2)have been fully characterized by X-ray crystal analysis,IR and microanalyses.Compounds 1 and 2 show optical transitions with band gaps of 2.17 and 1.84 eV,respectively.