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The self-assembly of Co(OAc)·4H2O with H2tbip and bipy (H2tbip = 5-tert-butyl isophthalic acid, bipy = 4,4’-bipyridine) generates one new complex, [Co3(tbip)2(Htbip)2(bipy)]n, which has been characterized by elemental analysis, X-ray diffraction, and IR spectroscopy. Single-crystal X-ray analysis reveals that it crystallizes in the triclinic space group P1 with a = 9.471(6), b = 12.597(8), c = 12.899(8), α = 84.660(7), β = 70.548(7), γ = 81.965(7)o, V = 1435.1(15)3, Mr = 1215.85, Dc = 1.407 g/cm3, Z = 1, F(000) = 629, μ(MoKα) = 0.926 mm-1, the final R = 0.0623 and wR = 0.1724. The complex consists of a tbip bridged trinuclear cobalt() unit and is further linked by 4,4’-bipyridine molecule to form a 2D supramolecular network.
The self-assembly of Co (OAc) · 4H2O with H2tbip and bipy (H2tbip = 5-tert-butyl isophthalic acid, bipy = 4,4’-bipyridine) (bipy)] n, which has been characterized by elemental analysis, X-ray diffraction, and IR spectroscopy. Single-crystal X-ray analysis shows that it crystallizes in the triclinic space group P1 with a = 9.471 (6), b = 12.597 8, c = 12.899 8, α = 84.660 (7), β = 70.548 (7), γ = 81.965 (7) o, V = 1435.1 (15) 3, Mr = 1215.85, Dc = 1.407 g / cm3, Z = 1, F (000) = 629, μ (MoKα) = 0.926 mm-1, the final R = 0.0623 and wR = 0.1724. The complex consists of a tbip bridged trinuclear cobalt () unit and is further linked by 4,4’-bipyridine molecule to form a 2D supramolecular network.