【摘 要】
：
FeX3(X = Cl, Br) were found to be very effective reagents and powerful catalysts for regioselective ring openings of a variety of N-tosylaziridines with them to
【机 构】
：
Department of Chemistry and Chemical Engineering, Taiyuan University of Technology,
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
FeX3(X = Cl, Br) were found to be very effective reagents and powerful catalysts for regioselective ring openings of a variety of N-tosylaziridines with them to afford the corresponding b-haloamines in good to excellent yields with high regioselectivity under mild conditions. At the same time, 13 new compounds were obtained firstly. Moreover, the b-bromoamine prepared could be transferred into b-nitroamine with NaNO2 in moderate yield.
FeX3 (X = Cl, Br) were found to be very effective reagents and powerful catalysts for regioselective ring openings of a variety of N-tosylaziridines with them to afford the corresponding b-haloamines in good to excellent yields with high regioselectivity under mild conditions. At the same time, 13 new compounds were obtained. Furthermore, the b-bromoamine prepared could be transferred into b-nitroamine with NaNO2 in a moderate yield.
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