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概述了多金属氧酸盐与ＴＴＦ类π电子有机给体形成的电荷转移盐研究的简短历史和新近进展，着重评述了它们的合成、结构、性质以及研究方法．
The brief history and recent progress of the charge-transfer salts of polyoxometalates with TTF-type π-electron donors are reviewed. Their synthesis, structure, properties and research methods are reviewed.