聚8,8'-二羟基-5,5'-偶氮苯二喹啉金属螯合物的合成及荧光性质

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Two polymeric chelates of 8 dihydroxyquinoline synthesized from biquinoline monomer with zinc acetate and copper acetate, respectively, are reported. The effects of reactant amount, reaction time on the yield of products have been studied. The IR and photoluminescence(PL) emission spectra of monomer and chelates have been recorded. The uniform films of polymeric azobenzolbiquinoline metal chelates were self assembled on hydroxy functional surfaces by alternately dipping in DMF solution of metal acetate and monomer. Two polymeric chelates of 8 dihydroxyquinoline synthase from biquinoline monomer with zinc acetate and copper acetate, respectively, are reported. The effects of reactant amount, reaction time on the yield of products have been studied. The IR and photoluminescence (PL) emission spectra of monomer and chelates have been recorded. The uniform films of polymeric azobenzolbiquinoline metal chelates were self assembled on hydroxy functional surfaces by alternately dipping in DMF solution of metal acetate and monomer.
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