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Reaction of TaCl(NMe2)4 (1) with KTp* [Tp* = tris(3,5-dimethylpyrazolyl)borohydride] yields two products: Tp*Ta(NMe2)4 (2), in which one N atom of the Tp* ligand binds to Ta, and [Tp*Ta(NMe2)4]· 2KTp* (3) where three N atoms of the Tp* ligand in [Tp*Ta(NMe2)4] (2a) bind to Ta. Addition of excess 1 to 3 did not exclude KTp*. Further reaction of 2 with oxygen affords Tp*BH(NMe2) (4). TpTa(NMe2)4 (5) has been synthesized by a similar procedure through the reaction of 1 with TpK [Tp=tris(pyrazolyl)borohydride]. Reactions of 3 and 5 with oxygen were also studied. 2, 4, and 5 were characterized by NMR, EA, and single-crystal X-ray diffraction.
Reaction of TaCl (NMe2) 4 (1) with KTp * [Tp * = tris (3,5-dimethylpyrazolyl) borohydride] yields two products: Tp * Ta * ligand binds to Ta, and [Tp * Ta (NMe2) 4] · 2KTp * (3) where three N atoms of the Tp * ligand in [Tp * Ta (NMe2) 4] (2a) excess 1 to 3 did not exclude KTp *. Further reaction of 2 with oxygen affords Tp * BH (NMe2) (4). TpTa (NMe2) 4 (5) has been synthesized by a similar procedure through the reaction of 1 with TpK [ Tp = tris (pyrazolyl) borohydride]. Reactions of 3 and 5 with oxygen were also studied. 2, 4, and 5 were characterized by NMR, EA, and single-crystal X-ray diffraction.