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The donor-acceptor complex HEC-TCNQ (HEC=9-hydroxyethylcarbazole;TCNQ = tetracyanoqinodimethane) has been synthesized. Under the illumination of Ar+ laser, the photoinduced charge transfer salt HEC+TCNQ- can be formed with a conductivity of at least one order of magnitude larger than that of HEC-TCNQ.