【摘 要】
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A new metal-organic coordination polymer [Zn(ipt)(im)2]2n(3nH2O 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR,
【机 构】
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Department of Chemistry,Jilin Normal University
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A new metal-organic coordination polymer [Zn(ipt)(im)2]2n(3nH2O 1 has been obtained by using hydrothermal synthesis and characterized by elemental analysis, IR, TG, fluorescence spectrum and single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group P21/n with a = 10.653(3), b = 17.891(6), c = 10.743(4)(A), β = 117.093(5)°, V = 1822.9(10)(A)3, Mr = 413.65, Dc = 1.507 g/cm3, μ(MoKα) = 1.390 mm-1, F(000) = 840, Z = 4, the final R = 0.0444 and wR = 0.1066 for 2434 observed reflections (I > 2σ(I)). Furthermore, compound 1 shows blue photoluminescent property at room temperature.
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