Morphologies,crystallization behavior and mechanical properties of polypropylene(PP)/syndiotactic 1,2-polybutadiene(s-1,2 PB)blends were investigated.Morphology observation shows the well dispersed domains of s-1,2 PB in PP matrix with the rather small domain sizes from 0.1 to 0.5μm when the s-1,2 PB content increases from 5%to 20%(mass fraction)in the blends,and the phase structure tends to become co-continuous as s-1,2 PB content further increases.Crystallization temperature(Tc)of PP component in the blends is fluctuated with the variation of s-1,2 PB content in the blends.Compatibilization,to some extent,between the two components is inferred from the examination of both morphology and crystallization behavior.Improvement of impact strength of PP toughened by s-1,2 PB becomes significant only in the case of s-1,2 PB content above 20%(mass fraction). Morphologies, crystallization behavior and mechanical properties of polypropylene (PP) / syndiotactic 1,2-polybutadiene (s-1,2 PB) blends were investigated. Morphology observations shows the well dispersed domains of s-1,2 PB in PP matrix with the rather small domain sizes from 0.1 to 0.5 μm when the s-1,2 PB content increases from 5% to 20% (mass fraction) in the blends, and the phase structure tends to become co-continuous as s-1,2 PB content further increases. Crystallization temperature (Tc) of PP component in the blends is fluctuated with the variation of s-1,2 PB content in the blends. Comppatibilization, to some extent, between the two components is inferred from the examination of both morphology and crystallization behavior. Impression of impact strength of PP toughened by s-1,2 PB as significant only in the case of s-1,2 PB content above 20% (mass fraction).