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The title complex has been synthesized with m-chlorobenzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous in the solvent mixture of water and methanol. Crystal data for this complex: triclinic, space group P1, a=0.8707(3) nm, b=1.2844(4) nm, c=1.6929(5) nm; α=75.430(5)°, β=77.562(5)°, γ=86.346(5)°, V=1.7894(9) nm3, Dc=1.456 g·cm-3, Z=2, F(000)=806. Final GooF=1.065, R1=0.0684, wR2=0.1275. The crystal stru-cture shows that the Cobaly ion is coordinated with four nitrogen atoms from two 1,10-phenanthroline molecules and two oxygen atoms from one m-chlorobenzoic acid molecule and one water molecule respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported.
The title complex has been synthesized with m-chlorobenzoic acid, 1,10-phenanthroline and cobalt perchlorate anhydrous in the solvent mixture of water and methanol. Crystal data for this complex: triclinic, space group P1, a = 0.8707 (3) nm, α = 75.430 (5) °, β = 77.562 (5) °, γ = 86.346 (5) °, V = 1.7894 (9) nm3, and Dc = 1.2844 1.456 g · cm -3, Z = 2, F (000) = 806. Final GooF = 1.065, R1 = 0.0684, wR2 = 0.1275. The crystal structure shows that the coupling structure is coordinated with four nitrogen atoms from two 1 , 10-phenanthroline molecules and two oxygen atoms from one m-chlorobenzoic acid molecule and one water molecule respectively, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported.