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采用水热法制备了h-MoO3·1/3H2O(化合物(1)),通过单晶X射线衍射对h-MoO3·1/3H2O的结构进行了进一步的确定,分析表明化合物h-MoO3·1/3H2O的结构基于由MoO6八面体形成的双链,通过共价键的结合形成了具有三维层状结构的多孔化合物,在化合物中含有由12元环和3元环堆积而成的两种隧道,其中水分子占据了12元环隧道.另外,作者研究了化合物(1)的红外光谱和拉曼光谱性质,并与其它相的化合物进行了对比.
The structure of h-MoO3 · 1 / 3H2O was further confirmed by single crystal X-ray diffraction. The results show that the compound h-MoO3 · 1 / 3H2O / 3H2O is based on the double chains formed by the MoO6 octahedra and covalently bonded to form a porous compound having a three-dimensional layer structure in which two kinds of tunnels including 12-membered ring and 3-membered ring are stacked , Of which the water molecule occupies a 12-membered ring tunnel.In addition, the author studied the infrared spectrum and the Raman spectrum of the compound (1) and compared them with the compounds of other phases.